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Articular cartilage (AC) is structurally and biochemically unique material for joint cartilage repair. To make AC tissue engineering (ACTE) more feasible, a biomimetic hydrogel is needed with ultrahigh viscoelasticity and faster degradation rate in order to match the native functional properties of AC. In this study, a poly (N-isopropylacrylamide) hydrogel (PNIPAm) with ultrahigh viscoelasticity and degradation rate for joint repair was fabricated by introducing a photopolymerization-responsive crosslinking unit to PNIPAm. The rheological properties of the hydrogel were evaluated by oscillatory shear rheometry. The biodegradation rate of the hydrogel was characterized by weight loss and dynamic mechanical analysis, and the mechanical properties of the hydrogel with different degradation time were also measured. The results show that the PNIPAm hydrogel has ultrahigh viscoelasticity and degradation rate and can maintain a long-lasting state for AC repair. The hydrogel with a degradation time of 14 days is suitable for joint repair. These PNIPAm hydrogels have potential applications for joint repair. the above-mentioned state of the art.
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